Silicon: Silicon is a gray, tetravalent, nonmetallic element
occurring abundantly in nature. Next to Oxygen it is the chief elementary
constituent of the earth's crust. The symbol for Silicon is Si its
atomic number is 14 and its atomic mass is 28.086. This element is almost
always found in various compounds both in nature and in industry, in nature you
find it in quartz, jasper, agate, flint, common beach sand, sandstone and many
other common rocks and materials. In industry we find it as the main component
in the most common building materials such as cement, bricks, glass and others.
Silicon as a Semiconductor: One of the
most important uses for Silicon in the second half of the twentieth century and
beyond is its ability to conduct electricity in a very controlled manner.
Relative to how many impurities or dopants (Boron, Phosphorus, Arsenic,
Antimony, etc.) are placed into its crystal structure. Simply put the more
dopant in the crystal lattice of Silicon the more it will conduct electricity.
In theory pure mono-crystalline Silicon will not conduct electricity very well
at all, the beauty of Silicon is that it can be made to take on dopants
precisely and after this doping it will normally remain stable under many
adverse conditions. Thus making the Silicon wafers an ideal Palette or surface
for the construction of today and tomorrow most advanced semiconductor devices.
The making of a Silicon Ingot: With all this talk of
sand and glass it may begin to over simplify a very complex process. The
process of growing Ingots of mono-crystalline Silicon with a uniform and
controlled dopant and oxygen content, and then to take these Ingots and grind,
slice and polish them into the final Prime wafers mostly free of defects that
major Fab's will use to build advanced semiconductor devices on, is nothing
short of a monumental task.
Raw Material: Silicon is the raw material of course; the crucible
is filled with pure Polysilicon chips. These chunks of Poly have been made from
sand by means of a complex reduction and purification process using
Trichlorosilane and Hydrogen. Then the Polysilicon is further distilled and
reduced and finally deposited on heated Titanium or Tantalum tubes. After
further processing it becomes the material you see it may be in a granular
form. The Poly is in a quartz container called a crucible and this material is
now ready to go on to the next processing step in the manufacturing of a high
quality Silicon ingot.
Polysilicon chips
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